A.Finish carpenter David Frane responds:
It's tempting to use plywood to make big doors, but, unfortunately,
it (even mdo) won't stay flat when exposed to the weather. Here
are three other ways to make doors the size you want:
The best way is to make real stile-and-rail doors. But that
requires skill at joinery and better stock than you can get at
most lumberyards. For doors this size, I'd want stiles and
rails that were a minimum of 2 1/4 inches thick. You'd have to
start with thick, dry material and use a jointer and planer to
straighten it and bring it down to size. The panels could be
3/8- or 1/2-inch plywood. This will give you the best doors,
but they'll be expensive and time consuming to build.

A simple rustic option would be to make old-fashioned shed
doors out of T&G boards. Most lumberyards stock this in a
#2 grade spruce or pine. The vertical face boards are fastened
to horizontal backer strips. Diagonals are applied to the back
side to keep the doors from sagging. The doors will be only as
straight and flat as the backers. Old-time carpenters
clinch-nailed the face boards, but I'd use galvanized drywall
screws to hold them. Some of the face boards will cup, and the
doors will rot if you don't do a good job of sealing and
painting the edges.
If you're determined to make plywood doors, use something
thinner than 3/4-inch mdo. The sheet will want to warp, and
it's easier to restrain thinner material. The doors will be
less likely to warp if you apply the fake stiles and rails to
both sides of the sheet. The applied pieces should be straight,
flat, and dry. For $30 to $40 you can get 3/8- or 1/2-inch mdo,
but be sure to get the kind with paper on both faces. If it was
me, I'd spring for okoume or exterior-grade birch, which are
more stable than mdo because they have more plies. They come in
metric thicknesses and are about twice the price of mdo.